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25 April 2024
 
  » arxiv » arxiv.0705.2291

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Self-reptation and slow topological time scale of knotted polymers
Enzo Orlandini ; Attilio L. Stella ; Carlo Vanderzande ; Francesco Zonta ;
Date 16 May 2007
Subject Statistical Mechanics (cond-mat.stat-mech); Soft Condensed Matter (cond-mat.soft)
AbstractWe investigate the Rouse dynamics of a flexible ring polymer with a prime knot. Within a Monte Carlo approach, we locate the knot, follow its diffusion, and observe the fluctuations of its length. We characterise a topological time scale, and show that it is related to a self-reptation of the knotted region. The associated dynamical exponent, $z_T=2.32pm.1$, can be related to that of the equilibrium knot length distribution and determines the behaviour of several dynamical quantities.
Source arXiv, arxiv.0705.2291
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