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25 April 2024
 
  » arxiv » cond-mat/0102049

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Generalized effective depletion potentials
A. A. Louis ; R. Roth ;
Date 3 Feb 2001
Journal J. Phys.: Condens. Matter 33, L777 (2001)
Subject Soft Condensed Matter; Statistical Mechanics | cond-mat.soft cond-mat.stat-mech
AbstractWe propose that the behavior of asymmetric binary fluid mixtures with a large class of attractive or repulsive interparticle interactions can be understood by mapping onto effective non-additive hard-sphere models. The latter are best analyzed in terms of their underlying depletion potentials which can be exactly scaled onto known additive ones. By tuning the non-additivity, a wide variety of attractive or repulsive generalized depletion potential shapes and associated phase behavior can be ``engineered’’, leading, for example, to two ways to stabilize colloidal suspensions by adding smaller particles.
Source arXiv, cond-mat/0102049
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