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Article overview
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Three-phase fractionation of polydisperse fluids | L. Bellier-Castella
; M. Baus
; H. Xu
; | Date: |
28 May 2001 | Subject: | Statistical Mechanics | cond-mat.stat-mech | Abstract: | It is shown that the van der Waals free-energy of polydisperse fluids, as introduced previously (L. Bellier-Castella, H. Xu and M. Baus, {J. Chem. Phys.} {113}, 8337 (2000)), predicts that for certain thermodynamic states (e.g. low temperatures and large polydispersities) the ordinary two-phase coexistences become metastable relative to a fractionation of the system into three phases, reducing thereby the polydispersity of each of the coexisting phases. | Source: | arXiv, cond-mat/0105522 | Services: | Forum | Review | PDF | Favorites |
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