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Adaptation of bulk constitutive equations to insoluble monolayer collapse at the air-water interface | | J P Kampf
; C W Frank
; E E Malmström
; C J Hawker
; | | Date: |
12 Mar 1999 | | Journal: | Science, 283 (5408), 1730-3 | | Abstract: | A constitutive equation based on stress-strain models of bulk solids was adapted to relate the surface pressure, compression rate, and temperature of an insoluble monolayer of monodendrons during collapse at the air-water interface. A power law relation between compression rate and surface pressure and an Arrhenius temperature dependence of the steady-state creep rate were observed in data from compression rate and creep experiments in the collapse region. These relations were combined into a single constitutive equation to calculate the temperature dependence of the collapse pressure with a maximum error of 5 percent for temperatures ranging from 10 degrees to 25 degrees C. | | Source: | PubMed, pmid10073937 | | Services: | Forum | Review | Favorites | |
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