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20 April 2024
 
  » arxiv » quant-ph/0101140

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Quantum Approach to a Derivation of the Second Law of Thermodynamics
Jochen Gemmer ; Alexander Otte ; Guenter Mahler ;
Date 30 Dec 2000
Subject quant-ph
AbstractWe re-interprete the microcanonical conditions in the quantum domain as constraints for the interaction of the "gas-subsystem" under consideration and its environment ("container"). The time-average of a purity-measure is found to equal the average over the respective path in Hilbert-space. We then show that for typical (degenerate or non-degenerate) thermodynamical systems almost all states within the allowed region of Hilbert-space have a local von Neumann-entropy S close to the maximum and a purity P close to its minimum, respectively. Typically thermodynamical systems should therefore obey the second law.
Source arXiv, quant-ph/0101140
Other source [GID 78095] pmid11289822
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