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20 April 2024
 
  » pubmed » pmid17678316

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Anomalous lattice response at the Mott transition in a quasi-2D organic conductor
M de Souza ; A Brühl ; Ch Strack ; B Wolf ; D Schweitzer ; M Lang ;
Date 20 Jul 2007
Journal Phys Rev Lett, 99 (3), 037003
AbstractDiscontinuous changes of the lattice parameters at the Mott metal-insulator transition are detected by high-resolution dilatometry on deuterated crystals of the layered organic conductor kappa-(BEDT-TTF)(2)Cu[N(CN)(2)]Br. The uniaxial expansivities uncover a striking and unexpected anisotropy, notably a zero effect along the in-plane c axis along which the electronic interactions are relatively strong. A huge thermal expansion anomaly is observed near the end point of the first-order transition line enabling us to explore the critical behavior with very high sensitivity. The analysis yields critical fluctuations with an exponent alpha approximately 0.8+/-0.15 at odds with the novel criticality recently proposed for these materials [Kagawa et al., Nature (London) 436, 534 (2005)]. Our data suggest an intricate role of the lattice degrees of freedom in the Mott transition for the present materials.
Source PubMed, pmid17678316
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