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23 April 2024 |
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Article overview
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Magnetic fullerenes inside single-wall carbon nanotubes | F Simon
; H Kuzmany
; B Náfrádi
; T Fehér
; L Forró
; F Fülöp
; A Jánossy
; L Korecz
; A Rockenbauer
; F Hauke
; A Hirsch
; | Date: |
29 Sep 2006 | Journal: | Phys Rev Lett, 97 (13), 136801 | Abstract: | C(59)N magnetic fullerenes were formed inside single-wall carbon nanotubes by vacuum annealing functionalized C(59)N molecules encapsulated inside the tubes. A hindered, anisotropic rotation of C(59)N was deduced from the temperature dependence of the electron spin resonance spectra near room temperature. Shortening of the spin-lattice relaxation time T(1) of C(59)N indicates a reversible charge transfer toward the host nanotubes above approximately 350 K. Bound C(59)N-C(60) heterodimers are formed at lower temperatures when C(60) is coencapsulated with the functionalized C(59)N. In the 10-300 K range, T(1) of the heterodimer shows a relaxation dominated by the conduction electrons on the nanotubes. | Source: | PubMed, pmid17026062 | Services: | Forum | Review | Favorites |
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