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25 April 2024
 
  » pubmed » pmid11060635

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X-Ray anomalous scattering study of a charge-ordered state in NaV2O5
H Nakao ; K Ohwada ; N Takesue ; Y Fujii ; M Isobe ; Y Ueda ; M Zimmermann ; J P Hill ; D Gibbs ; J C Woicik ; I Koyama ; Y Murakami ;
Date 13 Nov 2000
Journal Phys Rev Lett, 85 (20), 4349-52
AbstractCharge ordering of V4+ and V5+ in NaV2O5 has been studied by an x-ray diffraction technique using anomalous scattering near a vanadium K-absorption edge to critically enhance a contrast between the two ions. A dramatic energy dependence of the superlattice intensities is observed below T(C) = 35 K. The charge ordering pattern is the fully charged zigzag-type ladder with the unit cell 2ax2bx4c, but not the chain-type originally proposed for the spin-Peierls state. Charge disproportionation suggested in our model as the average valence V(4.5+/-delta(c)/2) is observed below T(C), showing continuous variation of delta(c) as a function of temperature.
Source PubMed, pmid11060635
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