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28 March 2024
 
  » pubmed » pmid11461208

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Phase separation in star-polymer-colloid mixtures
J Dzubiella ; A Jusufi ; C N Likos ; C von Ferber ; H Löwen ; J Stellbrink ; J Allgaier ; D Richter ; A B Schofield ; P A Smith ; W C Poon ; P N Pusey ;
Date 30 Jun 2001
Journal Phys Rev E, 64 (1 Pt 1), 010401
AbstractWe examine the demixing transition in star-polymer-colloid mixtures for star arm numbers f=2,6,16,32 and different star-polymer-colloid size ratios 0.18< or =q< or =0.50. Theoretically, we solve the thermodynamically self-consistent Rogers-Young integral equations for binary mixtures using three effective pair potentials obtained from direct molecular computer simulations. The numerical results show a spinodal instability. The demixing binodals are approximately calculated and found to be consistent with experimental observations.
Source PubMed, pmid11461208
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