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25 April 2024
 
  » arxiv » 0904.3205

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Phonon surface mapping of graphite: disentangling quasi--degenerate phonon dispersions
A. Grüneis ; J. Serrano ; A. Bosak ; M. Lazzeri ; S.L. Molodtsov ; L. Wirtz ; C. Attaccalite ; M. Krisch ; A. Rubio ; F. Mauri ; T. Pichler ;
Date 21 Apr 2009
AbstractThe two-dimensional mapping of the phonon dispersions around the $K$ point of graphite by inelastic x-ray scattering is provided. The present work resolves the longstanding issue related to the correct assignment of transverse and longitudinal phonon branches at $K$. We observe an almost degeneracy of the three TO, LA and LO derived phonon branches and a strong phonon trigonal warping. Correlation effects renormalize the Kohn anomaly of the TO mode, which exhibits a trigonal warping effect opposite to that of the electronic band structure. We determined the electron--phonon coupling constant to be 166$ m(eV/AA)^2$ in excellent agreement to $GW$ calculations. These results are fundamental for understanding angle-resolved photoemission, double--resonance Raman and transport measurements of graphene based systems.
Source arXiv, 0904.3205
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