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20 April 2024
 
  » arxiv » 0906.0929

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Single-particle and collective slow dynamics of colloids in porous confinement
Jan Kurzidim ; Daniele Coslovich ; Gerhard Kahl ;
Date 4 Jun 2009
AbstractUsing molecular dynamics simulations we study the slow dynamics of a hard sphere fluid confined in a disordered porous matrix. The presence of both discontinuous and continuous glass transitions as well as the complex interplay between single-particle and collective dynamics are well captured by a recent extension of mode-coupling theory for fluids in porous media. The degree of universality of the mode-coupling theory predictions for related models of colloids is studied by introducing size-disparity between fluid and matrix particles, as well as softness in the interactions.
Source arXiv, 0906.0929
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