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20 April 2024
 
  » arxiv » 1001.4502

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Electroconvective instability of self-similar equilibria
E. Demekhin ; S. Polyanskikh ; Yury Shtemler ;
Date 25 Jan 2010
AbstractStability of electro-hydrodynamic processes between ion-exchange membranes is investigated. Solutions of the equilibrium problem which represents the balance between diffusion and electro-migration are commonly described in an one-dimensional (1D) steady-state approximation. In the present work a novel class of the 1D unsteady self-similar equilibrium solution is developed asymptotically in small Debye length, epsilon, and large distance between membranes (both made dimensionless with the diffusion-layer thickness). First, the 1D unsteady family of self-similar equilibrium solutions is developed. Then, a linear stability of the self-similar solutions slowly varied with time is investigated in the limit of small epsilonand the marginal stability curves are obtained. Method of matched asymptotics is applied provided that only the outer solution is considered, ignoring the inner solutions. The success of the analysis is provided by transforming the equations to the divergent type (nabla G=0) with the patching conditions applied to the outer values of the functions, which constitute the expression G. The interface instability of the boundary of space charge region is found to be the main reason of instability of 1D equilibrium solution}. The self-similar solution and marginal stability curves are in a fair agreement with those obtained by direct numerical simulations of the entire problem at intermediately large times for which the dimensionless distance between membranes is large.
Source arXiv, 1001.4502
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