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20 April 2024
 
  » arxiv » 1008.5229

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Quantitative atomic spectroscopy for primary thermometry
Gar-Wing Truong ; Eric F. May ; Thomas M. Stace ; Andre N. Luiten ;
Date 31 Aug 2010
AbstractQuantitative spectroscopy has been used to measure accurately the Doppler-broadening of atomic transitions in $^{85}$Rb vapor. By using a conventional platinum resistance thermometer and the Doppler thermometry technique, we were able to determine $k_B$ with a relative uncertainty of $4.1 imes 10^{-4}$, and with a deviation of $2.7 imes 10^{-4}$ from the expected value. Our experiment, using an effusive vapour, departs significantly from other Doppler-broadened thermometry (DBT) techniques, which rely on weakly absorbing molecules in a diffusive regime. In these circumstances, very different systematic effects such as magnetic sensitivity and optical pumping are dominant. Using the model developed recently by Stace and Luiten, we estimate the perturbation due to optical pumping of the measured $k_B$ value was less than $4 imes 10^{-6}$. The effects of optical pumping on atomic and molecular DBT experiments is mapped over a wide range of beam size and saturation intensity, indicating possible avenues for improvement. We also compare the line-broadening mechanisms, windows of operation and detection limits of some recent DBT experiments.
Source arXiv, 1008.5229
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