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23 April 2024
 
  » arxiv » 1010.1183

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Magnetostrictive Neel ordering of the spin-5/2 ladder compound BaMn2O3: distortion-induced lifting of geometrical frustration
M. Valldor ; O. Heyer ; A.C. Komarek ; A. Senyshyn ; M. Braden ; T. Lorenz ;
Date 6 Oct 2010
AbstractThe crystal structure and the magnetism of BaMn$_2$O$_3$ have been studied by thermodynamic and by diffraction techniques using large single crystals and powders. BaMn$_2$O$_3$ is a realization of a $S = 5/2$ spin ladder as the magnetic interaction is dominant along 180$^circ$ Mn-O-Mn bonds forming the legs and the rungs of a ladder. The temperature dependence of the magnetic susceptibility exhibits well-defined maxima for all directions proving the low-dimensional magnetic character in BaMn$_2$O$_3$. The susceptibility and powder neutron diffraction data, however, show that BaMn$_2$O$_3$ exhibits a transition to antiferromagnetic order at 184 K, in spite of a full frustration of the nearest-neighbor inter-ladder coupling in the orthorhombic high-temperature phase. This frustration is lifted by a remarkably strong monoclinic distortion which accompanies the magnetic transition.
Source arXiv, 1010.1183
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