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25 April 2024
 
  » arxiv » 1106.0662

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Quasi-one-dimensional antiferromagnetism and multiferroicity in CuCrO$_4$
J. M. Law ; P. Reuvekamp ; R. Glaum ; C. Lee ; J. Kang ; M.-H. Whangbo ; R. K. Kremer ;
Date 3 Jun 2011
AbstractThe bulk magnetic properties of the new quasi-one-dimensional Heisenberg antiferromagnet, CuCrO$_4$, were characterized by magnetic susceptibility, heat capacity, optical spectroscopy, EPR and dielectric capacitance measurements and density functional evaluations of the intra- and interchain spin exchange interactions. We found type-II multiferroicity below the N’{e}el temperature of 8.2(5) K, arising from competing antiferromagnetic nearest-neighbor ($J_{ m nn}$) and next-nearest-neighbor ($J_{ m nnn}$) intra-chain spin exchange interactions. Experimental and theoretical results indicate that the ratio $J_{ m nn}/J_{ m nnn}$ is close to 2, putting CuCrO$_4$ in the vicinity of the Majumdar-Ghosh point.
Source arXiv, 1106.0662
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