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19 April 2024
 
  » arxiv » 1202.4340

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Observation of superconductivity at 30 K~46 K in AxFe2Se2 (A = Li, Na, Ba, Sr, Ca, Yb, and Eu)
T. P. Ying ; X. L. Chen ; G. Wang ; S. F. Jin ; T. T. Zhou ; X. F. Lai ; H. Zhang ; W. Y. Wang ;
Date 20 Feb 2012
AbstractNew iron selenide superconductors by intercalating smaller-sized alkali metals (Li, Na) and alkaline earths using high-temperature routes have been pursued ever since the discovery of superconductivity at about 30 K in (K, Rb, or Cs)Fe2Se2, but all have failed so far. Here we demonstrate that a series of superconductors with enhanced Tc = 30~46 K can be obtained by intercalating metals, Li, Na, Ba, Sr, Ca, Yb, and Eu in between FeSe layers by the liquid ammonia method at room temperature. The findings provide a new starting point for studying the properties of these superconductors and an effective synthetic route for the exploration of new superconductors as well.
Source arXiv, 1202.4340
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