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Nonlinear response theory for Markov processes: Simple models for glassy relaxation | | Gregor Diezemann
; | | Date: |
8 Mar 2012 | | Abstract: | The theory of nonlinear response for Markov processes obeying a master
equation is formulated in terms of time-dependent perturbation theory for the
Green’s functions and general expressions for the response functions up to
third order in the external field are given. The nonlinear response is
calculated for a model of dipole reorientations in an asymmetric double well
potential, a standard model in the field of dielectric spectroscopy. The static
nonlinear response is finite with the exception of a certain temperature $T_0$
determined by the value of the asymmetry. In a narrow temperature range around
$T_0$, the modulus of the frequency-dependent cubic response shows a peak at a
frequency on the order of the relaxation rate and it vanishes for both, low
frequencies and high frequencies. At temperatures at which the static response
is finite (lower and higher than $T_0$), the modulus is found to decay
monotonously from the static limit to zero at high frequencies. In addition,
results of calculations for a trap model with a Gaussian density of states are
presented. In this case, the cubic response depends on the specific dynamical
variable considered and also on the way the external field is coupled to the
kinetics of the model. In particular, a set of different dynamical variables is
considered that gives rise to identical shapes of the linear susceptibility and
only to different temperature dependencies of the relaxation times. It is found
that the frequency dependence of the nonlinear response functions, however,
strongly depends on the particular choice of the variables. The results are
discussed in the context of recent theoretical and experimental findings
regarding the nonlinear response of supercooled liquids and glasses. | | Source: | arXiv, 1203.1785 | | Services: | Forum | Review | PDF | Favorites | |
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