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29 March 2024 |
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Article overview
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Spin dynamics of molecular nanomagnets fully unraveled by four-dimensional inelastic neutron scattering | M. L. Baker
; T. Guidi
; S. Carretta
; J. Ollivier
; H. Mutka
; H. U. Güdel
; G. A. Timco
; E. J. L. McInnes
; G. Amoretti
; R. E. P. Winpenny
; P. Santini
; | Date: |
23 Aug 2012 | Abstract: | Molecular nanomagnets are among the first examples of spin systems of finite
size and have been test-beds for addressing a range of elusive but important
phenomena in quantum dynamics. In fact, for short-enough timescales the spin
wavefunctions evolve coherently according to the an appropriate cluster
spin-Hamiltonian, whose structure can be tailored at the synthetic level to
meet specific requirements. Unfortunately, to this point it has been impossible
to determine the spin dynamics directly. If the molecule is sufficiently
simple, the spin motion can be indirectly assessed by an approximate model
Hamiltonian fitted to experimental measurements of various types. Here we show
that recently-developed instrumentation yields the four-dimensional
inelastic-neutron scattering function S(Q,E) in vast portions of reciprocal
space and enables the spin dynamics to be determined with no need of any model
Hamiltonian. We exploit the Cr8 antiferromagnetic ring as a benchmark to
demonstrate the potential of this new approach. For the first time we extract a
model-free picture of the quantum dynamics of a molecular nanomagnet. This
allows us, for example, to examine how a quantum fluctuation propagates along
the ring and to directly test the degree of validity of the
N’{e}el-vector-tunneling description of the spin dynamics. | Source: | arXiv, 1208.4785 | Services: | Forum | Review | PDF | Favorites |
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