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25 April 2024
 
  » arxiv » 1301.3769

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Huge field-effect surface charge injection and conductance modulation in metallic thin films by electrochemical gating
M. Tortello ; A. Sola ; Kanudha Sharda ; F. Paolucci ; J. R. Nair ; C. Gerbaldi ; D. Daghero ; R. S. Gonnelli ;
Date 16 Jan 2013
AbstractThe field-effect technique, popular thanks to its application in common field-effect transistors, is here applied to metallic thin films by using as a dielectric a novel polymer electrolyte solution. The maximum injected surface charge, determined by a suitable modification of a classic method of electrochemistry called double-step chronocoulometry, reached some units in 10^15 charges/cm^2. At room temperature, relative variations of resistance up to 8%, 1.9% and 1.6% were observed in the case of gold, silver and copper, respectively and, if the films are thick enough (> 25 nm), results can be nicely explained within a free-electron model with parallel resistive channels. The huge charge injections achieved make this particular field-effect technique very promising for a vast variety of materials such as unconventional superconductors, graphene and 2D-like materials.
Source arXiv, 1301.3769
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