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25 April 2024 |
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Interstellar detection of c-C3D2 | S. Spezzano
; S. Brünken
; P. Schilke
; P. Caselli
; K. M. Menten
; M. C. McCarthy
; L. Bizzocchi
; S. P. Trevino-Morales
; Y. Aikawa
; S. Schlemmer
; | Date: |
8 May 2013 | Abstract: | We report the first interstellar detection of c-C3D2. The doubly deuterated
cyclopropenylidene, a carbene, has been detected toward the starless cores TMC-
1C and L1544 using the IRAM 30m telescope. The J(Ka,Kc) = 3(0,3)-2(1,2),
3(1,3)-2(0,2), and 2(2,1)-1(1,0) transitions of this species have been observed
at 3 mm in both sources. The expected 1:2 intensity ratio has been found in the
3(0,3)-2(1,2) and 3(1,3)-2(0,2) lines, belonging to the para and ortho species
respectively. We also observed lines of the main species, c-C3H2, the singly
deuterated c-C3HD, and the species with one 13C off of the principal axis of
the molecule, c-H13CC2H. The lines of c-C3D2 have been observed with high
signal to noise ratio, better than 7.5 sigma in TMC-1C and 9 sigma in L1544.
The abundance of doubly deuterated cyclopropenylidene with respect to the
normal species is found to be (0.4 - 0.8)% in TMC-1C and (1.2 - 2.1)% in L1544.
The deuteration of this small hydrocarbon ring is analysed with a comprehensive
gas-grain model, the first including doubly deuterated species. The observed
abundances of c-C3D2 can be explained solely by gas-phase processes, supporting
the idea that c-C3H2 is a good indicator of gas-phase deuteration. | Source: | arXiv, 1305.1954 | Services: | Forum | Review | PDF | Favorites |
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