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19 April 2024
 
  » arxiv » cond-mat/0302474

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Exactly solvable model of A + A o 0 reactions on a heterogeneous catalytic chain
G.Oshanin ; O.Benichou ; A.Blumen ;
Date 24 Feb 2003
Subject Statistical Mechanics | cond-mat.stat-mech
Affiliation LPTL, Paris 6, France; LPMC, College de France, France; Theoretical Polymer Physics, University of Freiburg, Germany
AbstractWe present an exact solution describing equilibrium properties of the catalytically-activated A + A o 0 reaction taking place on a one-dimensional lattice, where some of the sites possess special "catalytic" properties. The A particles undergo continuous exchanges with the vapor phase; two neighboring adsorbed As react when at least one of them resides on a catalytic site (CS). We consider three situations for the CS distribution: regular, annealed random and quenched random. For all three CS distribution types, we derive exact results for the disorder-averaged pressure and present exact asymptotic expressions for the particles’ mean density. The model studied here furnishes another example of a 1D Ising-type system with random multi-site interactions which admits an exact solution.
Source arXiv, cond-mat/0302474
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