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Optimal protocols and the Jarzynski equality | | Stuart J. Davie
; Owen G. Jepps
; Lamberto Rondoni
; James C. Reid
; Debra J. Searles
; | | Date: |
13 Nov 2013 | | Abstract: | The Jarzynski Equality is a well-known and widely used identity, relating the
free energy difference between two states of a system to the work done over
some arbitrary, nonequilibrium transformation between the two states. Despite
being valid for both stochastic and deterministic systems, we show that the
optimal transformation protocol for the deterministic case seems to differ from
that predicated from an analysis of the stochastic dynamics. In addition, it is
shown that for certain situations, more dissipative processes can sometimes
lead to better numerical results for the free energy differences. | | Source: | arXiv, 1311.3018 | | Services: | Forum | Review | PDF | Favorites | |
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