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25 April 2024
 
  » arxiv » 1505.7222

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Cryogenic micro-calorimeters for mass spectrometric identification of neutral molecules and molecular fragments
O. Novotný ; S. Allgeier ; C. Enss ; A. Fleischmann ; L. Gamer ; D. Hengstler ; S. Kempf ; C. Krantz ; A. Pabinger ; C. Pies ; D. W. Savin ; D. Schwalm ; A. Wolf ;
Date 27 May 2015
AbstractWe have systematically investigated the energy resolution of a magnetic micro-calorimeter (MMC) for atomic and molecular projectiles at impact energies ranging from $Eapprox13$ to 150~keV. For atoms we obtained absolute energy resolutions down to $Delta E approx 120$~eV and relative energy resolutions down to $Delta E/Eapprox10^{-3}$. We also studied in detail the MMC energy-response function to molecular projectiles of up to mass 56~u. We have demonstrated the capability of identifying neutral fragmentation products of these molecules by calorimetric mass spectrometry. We have modeled the MMC energy-response function for molecular projectiles and conclude that backscattering is the dominant source of the energy spread at the impact energies investigated. We have successfully demonstrated the use of a detector absorber coating to suppress such spreads. We briefly outline the use of MMC detectors in experiments on gas-phase collision reactions with neutral products. Our findings are of general interest for mass spectrometric techniques, particularly for those desiring to make neutral-particle mass measurements.
Source arXiv, 1505.7222
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