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16 April 2024
 
  » arxiv » 1701.4376

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First detection of methylisocyanate (CH3NCO) in a solar-type protostar
R. Martín-Doménech ; V. Rivilla ; I. Jiménez-Serra ; D. Quenard ; L. Testi ; J. Martín-Pintado ;
Date 16 Jan 2017
AbstractWe report the first detection of the prebiotic complex organic molecule CH$_3$NCO in a solar-type protostar, IRAS16293-2422 B. This species is one of the most abundant complex organic molecule detected on the surface of the comet 67P/Churyumov-Gerasimenko, and in the insterstellar medium it has only been found in hot cores around high-mass protostars. We have used multi-frequency ALMA observations from 90 GHz to 350 GHz covering 11 unblended transitions of CH$_3$NCO and 40 more transitions that appear blended with emission from other molecular species. Our Local Thermodynamic Equilibrium analysis provides an excitation temperature of 232$pm$41 K and a column density of (7.9$pm$1.7)$ imes$10$^{15}$ cm$^{-2}$, which implies an abundance of (7$pm$2)$ imes$10$^{-10}$ with respect to molecular hydrogen. The derived column density ratios CH$_3$NCO/HNCO, CH$_3$NCO/NH$_2$CHO, and CH$_3$NCO/CH$_3$CN are $sim$0.3, $sim$0.8, and $sim$0.2, respectively, which are different from those measured in hot cores and in comet 67P/Churyumov-Gerasimenko. Our chemical modelling of CH$_3$NCO reproduces well the abundances and column density ratios CH$_3$NCO/HNCO and CH$_3$NCO/NH$_2$CHO measured in IRAS16293-2422 B, suggesting that the production of CH$_3$NCO could occur mostly via gas-phase chemistry after the evaporation of HNCO from dust grains.
Source arXiv, 1701.4376
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