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20 April 2024
 
  » arxiv » cond-mat/0412153

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High pressure high temperature (HPHT) synthesis and magnetization of Magneto-Superconducting RuSr2(LnCe2)Cu2O12.25 (Ru-1232) compounds (Ln = Y and Dy)
V.P.S. Awana ; H. Kishan ; T. Kawashima ; E. Takayama-Muromachi ; C A. Cardoso ;
Date 7 Dec 2004
Journal MMM Conf. Proc. for J. Appl. Phys. (2005)
Subject Superconductivity; Strongly Correlated Electrons | cond-mat.supr-con cond-mat.str-el
AffiliationNPL, New Delhi India), T. Kawashima and E. Takayama-Muromachi (NIMS, Tsukuba, Japan), C A. Cardoso (UDM, USA
AbstractRuSr2(LnCe2)Cu2O12.25 (Ru-1232) compounds with Ln = Y and Dy being synthesized by high pressure high temperature (6GPa, 12000C) solid state synthesis route do crystallize in space group P4/mmm in near single phase form with small quantities of SrRuO3 and RuSr2(RE1.5Ce0.5)Cu2O10 (Ru-1222). Both samples exhibit magnetic transitions (Tmag.) at ~90 K with significant branching of zfc (zero-field-cooled) and fc (field-cooled) magnetization and a sharp cusp in zfc at ~ 70 K, followed by superconducting transitions at ~ 30 K. Both compounds show typical ferromagnetic hysteresis loops in magnetic moment (M) versus field (H) magnetization right upto Tmag. i.e. < 90K. To our knowledge these are the first successfully synthesized Ru-1232 compounds in near single phase with lanthanides including Y and Dy. The results are compared with widely reported Gd/Ru-1222 and Ru-1212 (RuSr2GdCu2O8) compounds. In particular, it seems that the Ru moments magnetic ordering temperature (Tmag.) scales with the c-direction distance between magnetic RuO6 octahedras in Ru-1212/1222 or 1232 systems.
Source arXiv, cond-mat/0412153
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