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19 April 2024
 
  » arxiv » cond-mat/0501577

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Spin gap formation in the quantum spin systems TiOX, X=Cl and Br
P. Lemmens ; K.Y. Choi ; R. Valenti ; T. Saha-Dasgupta ; E. Abel ; Y.S. Lee ; F.C. Chou ;
Date 24 Dec 2004
Subject Strongly Correlated Electrons | cond-mat.str-el
AbstractIn the layered quantum spin systems TiOCl and TiOBr the magnetic susceptibility shows a very weak temperature dependence at high temperatures and transition-induced phenomena at low temperatures. There is a clear connection of the observed transition temperatures to the distortion of the octahedra and the layer separation. Band structure calculations point to a relation of the local coordinations and the dimensionality of the magnetic properties. While from magnetic Raman scattering only a small decrease of the magnetic exchange by -5-10% is derived comparing TiOCl with TiOBr, the temperature dependence of the magnetic susceptibility favors a much bigger change.
Source arXiv, cond-mat/0501577
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