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Tetratic Order in the Phase Behavior of a Hard-Rectangle System | A. Donev
; J. Burton
; F. H. Stillinger
; S. Torquato
; | Date: |
23 Aug 2005 | Subject: | Statistical Mechanics; Disordered Systems and Neural Networks | cond-mat.stat-mech cond-mat.dis-nn | Abstract: | Previous Monte Carlo investigations by Wojciechowski emph{et al.} have found two unusual phases in two-dimensional systems of anisotropic hard particles: a tetratic phase of four-fold symmetry for hard squares [Comp. Methods in Science and Tech., 10: 235-255, 2004], and a nonperiodic degenerate solid phase for hard-disk dimers [Phys. Rev. Lett., 66: 3168-3171, 1991]. In this work, we study a system of hard rectangles of aspect ratio two, i.e., hard-square dimers (or dominos), and demonstrate that it exhibits a solid phase with both of these unusual properties. The solid shows tetratic, but not nematic, order, and it is nonperiodic having the structure of a random tiling of the square lattice with dominos. We obtain similar results with both a classical Monte Carlo method using true rectangles and a novel molecular dynamics algorithm employing rectangles with rounded corners. It is remarkable that such simple convex two-dimensional shapes can produce such rich phase behavior. Although we have not performed exact free-energy calculations, we expect that the random domino tiling is thermodynamically stabilized by its degeneracy entropy, well-known to be $1.79k_{B}$ per particle from previous studies of the dimer problem on the square lattice. Our observations are consistent with a KTHNY two-stage phase transition scenario with two continuous phase transitions, the first from isotropic to tetratic liquid, and the second from tetratic liquid to solid. | Source: | arXiv, cond-mat/0508550 | Services: | Forum | Review | PDF | Favorites |
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