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Calculation of the Phase Behavior of Lipids | | M. Mueller
; M. Schick (University of Washington
; Seattle
; | | Date: |
24 Feb 1998 | | Subject: | Statistical Mechanics | cond-mat.stat-mech | | Affiliation: | University of Washington, Seattle (U.S.A.) | | Abstract: | The self-assembly of monoacyl lipids in solution is studied employing a model in which the lipid’s hydrocarbon tail is described within the Rotational Isomeric State framework and is attached to a simple hydrophilic head. Mean-field theory is employed, and the necessary partition function of a single lipid is obtained via a partial enumeration over a large sample of molecular conformations. The influence of the lipid architecture on the transition between the lamellar and inverted-hexagonal phases is calculated, and qualitative agreement with experiment is found. | | Source: | arXiv, cond-mat/9802257 | | Services: | Forum | Review | PDF | Favorites | |
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