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22 March 2025
 
  » arxiv » 2201.00289

 Article overview



Nonvolatile Electric-Field Control of Inversion Symmetry
Lucas Caretta ; Yu-Tsun Shao ; Jia Yu ; Antonio B. Mei ; Bastien F. Grosso ; Cheng Dai ; Piush Behera ; Daehun Lee ; Margaret McCarter ; Eric Parsonnet ; Harikrishnan K.P. ; Fei Xue ; Ed Barnard ; Steffen Ganschow ; Archana Raja ; Lane W. Martin ; Long-Qing Chen ; Manfred Fiebig ; Keji Lai ; Nicola A. Spaldin ; David A. Muller ; Darrell G. Schlom ; Ramamoorthy Ramesh ;
Date 2 Jan 2022
AbstractIn condensed-matter systems, competition between ground states at phase boundaries can lead to significant changes in material properties under external stimuli, particularly when these ground states have different crystal symmetries. A key scientific and technological challenge is to stabilize and control coexistence of symmetry-distinct phases with external stimuli. Using BiFeO3 (BFO) layers confined between layers of the dielectric TbScO3 as a model system, we stabilize the mixed-phase coexistence of centrosymmetric and non-centrosymmetric BFO phases with antipolar, insulating and polar, semiconducting behavior, respectively at room temperature. Application of in-plane electric (polar) fields can both remove and introduce centrosymmetry from the system resulting in reversible, nonvolatile interconversion between the two phases. This interconversion between the centrosymmetric insulating and non-centrosymmetric semiconducting phases coincides with simultaneous changes in the non-linear optical response of over three orders of magnitude, a change in resistivity of over five orders of magnitude, and a change in the polar order. Our work establishes a materials platform allowing for novel cross-functional devices which take advantage of changes in optical, electrical, and ferroic responses.
Source arXiv, 2201.00289
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