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17 January 2025

» arxiv » 2301.00404

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Template Mediated Formation of Colloidal Two-Dimensional Tin Telluride Nanosheets and the Role of the Ligands
Fagui He ; Eugen Klein ; Stephan Bartling ; Siavash Saeidpour ; Björn Corzilius ; Rostyslav Lesyuk ; Christian Klinke ;
Date:	1 Jan 2023
Abstract:	We report the colloidal synthesis of 2D SnTe nanosheets through precursor hot-injection in a nonpolar solvent. During the reaction, an important intermediate - Sn-template - is formed which defines the confined growth of SnTe. This "flake-like" structure gives the first evidence for the possible 2D morphology formation prior to the anion precursor injection (TOP-Te). Additionally, we explore the role of each ligand in the reaction process. Thus, we explain the formation and morphology evolution of 2D SnTe nanostructures from a mechanism perspective as well as the role of each ligand on the molecular scale. The interplay of ligands provides the necessary conditions for the realization of stable low-dimensional SnTe nanomaterials with tunable size and shape.
Source:	arXiv, 2301.00404
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