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Model for the free-volume distributions of equilibrium fluids | | William P. Krekelberg
; Venkat Ganesan
; Thomas M. Truskett
; | | Date: |
1 Jun 2006 | | Journal: | J. Chem. Phys. 124, 214502 (2006) | | Subject: | Soft Condensed Matter | | Abstract: | We introduce and test via molecular simulation a simple model for predicting the manner in which interparticle interactions and thermodynamic conditions impact the single-particle free-volume distributions of equilibrium fluids. The model suggests a scaling relationship for the density-dependent behavior of the hard-sphere system. It also predicts how the second virial coefficients of fluids with short-range attractions affect their free-volume distributions. | | Source: | arXiv, cond-mat/0606044 | | Services: | Forum | Review | PDF | Favorites | |
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