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19 April 2024
 
  » arxiv » cond-mat/0606445

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Orbitally driven spin-singlet dimerization in $S$=1 La$_{4}$Ru$_{2}$O$_{10}$
Hua Wu ; Z. Hu ; T. Burnus ; J. D. Denlinger ; P. G. Khalifah ; D. Mandrus ; L.-Y. Jang ; H. H. Hsieh ; A. Tanaka ; K. S. Liang ; J. W. Allen ; R. J. Cava ; D. I. Khomskii ; L. H. Tjeng ;
Date 16 Jun 2006
Journal Phys. Rev. Lett. 96, 256402 (2006)
Subject Strongly Correlated Electrons
AbstractUsing x-ray absorption spectroscopy at the Ru-$L_{2,3}$ edge we reveal that the Ru$^{4+}$ ions remain in the $S$=1 spin state across the rare 4d-orbital ordering transition and spin-gap formation. We find using local spin density approximation + Hubbard U (LSDA+U) band structure calculations that the crystal fields in the low temperature phase are not strong enough to stabilize the $S$=0 state. Instead, we identify a distinct orbital ordering with a significant anisotropy of the antiferromagnetic exchange couplings. We conclude that La$_{4}$Ru$_{2}$O$_{10}$ appears to be a novel material in which the orbital physics drives the formation of spin-singlet dimers in a quasi 2-dimensional $S$=1 system.
Source arXiv, cond-mat/0606445
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