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19 April 2024
 
  » arxiv » cond-mat/0606452

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An iron(III) phosphonate cluster containing a nonanuclear ring
H. C. Yao ; J. J. Wang ; Y. S. Ma ; O. Waldmann ; W. X. Du ; Y. Song ; Y. Z. Li ; L. M. Zheng ; S. Decurtins ; X. Q. Xin ;
Date 16 Jun 2006
Journal Chem. Commun., 1745 (2006)
AbstractThis communication reports the first example of cyclic ferric clusters with an odd number of iron atoms capped by phosphonate ligands, namely, [Fe9(m-OH)7(m-O)2(O3PC6H9)8-(py)12]. The magnetic studies support a S = 1/2 ground state with an exchange coupling constant of about J = -30 K.
Source arXiv, cond-mat/0606452
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