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25 April 2024
 
  » arxiv » cond-mat/0606518

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X-ray absorption spectroscopy on layered cobaltates Na_xCoO_2
T. Kroll ; M. Knupfer ; J. Geck ; C. Hess ; T. Schwieger ; G. Krabbes ; C. Sekar ; D.R. Batchelor ; H. Berger ; B. Buechner ;
Date 20 Jun 2006
Subject Strongly Correlated Electrons
AbstractMeasurements of polarization and temperature dependent soft x-ray absorption have been performed on Na_xCoO_2 single crystals with x=0.4 and x=0.6. They show a deviation of the local trigonal symmetry of the CoO_6 octahedra, which is temperature independent in a temperature range between 25 K and 372 K. This deviation was found to be different for Co^{3+} and Co^{4+} sites. With the help of a cluster calculation we are able to interpret the Co L_{23}-edge absorption spectrum and find a doping dependent energy splitting between the t_{2g} and the e_g levels (10Dq) in Na_xCoO_2.
Source arXiv, cond-mat/0606518
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