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28 March 2024
 
  » arxiv » cond-mat/0606544

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Molecular Self-Assembly of Jointed Molecules on a Metallic Substrate: From Single Molecule to Monolayer
T. Zambelli ; S. Goudeau ; J. Lagoute ; A. Gourdon ; X. Bouju ; S. Gauthier ; PDF only ;
Date 21 Jun 2006
Subject Materials Science
AbstractBecause of its promising contribution to the bottom-up approach for nanofabrication of complex molecular architectures, self-organization is widely studied nowadays. Numerous studies have tackled supramolecular chirality or low-dimensional molecular nanostructures using in most cases small and rigid molecules adsorbed on metallic substrates. In this situation, self-assembled structures can be understood in relative simple terms considering molecule-molecule versus molecule-substrate interactions. In contrast, the case of large and three-dimensional molecules which can adopt different adsorption conformations is more complex. Here, we investigate the self-assembly of V-Landers molecules (C108H104) on Cu(100) by STM at room temperature under ultrahigh vacuum. This molecule is constituted of a central poly-aromatic board linked by sigma bonds to four 3,5-di-tert-butylphenyl legs.
Source arXiv, cond-mat/0606544
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