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11 December 2024
 
  » arxiv » cond-mat/9710348

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Dynamics of Phase Behavior of a Polymer Blend Under Shear Flow
Tao Sun ; Anna C. Balazs ; David Jasnow ;
Date 31 Oct 1997
Subject Soft Condensed Matter | cond-mat.soft
AbstractWe study the dynamics of the phase behavior of a polymer blend in the presence of shear flow. By adopting a two fluid picture and using a generalization of the concept of material derivative, we construct kinetic equations that describe the phase behavior of polymer blends in the presence of external flow. A phenomenological form for the shear modulus for the blend is proposed. The study indicates that a nonlinear dependence of the shear modulus of the blend on the volume fraction of one of the species is crucial for a shift in the stability line to be induced by shear flow.
Source arXiv, cond-mat/9710348
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