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26 April 2024
 
  » pubmed » pmid12785964

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Failure of Russell-Saunders coupling in the 5f states of plutonium
K T Moore ; M A Wall ; A J Schwartz ; B W Chung ; D K Shuh ; R K Schulze ; J G Tobin ;
Date 16 May 2003
Journal Phys Rev Lett, 90 (19), 196404
AbstractUsing high energy-electron energy loss spectroscopy, transmission electron microscopy, and synchrotron-radiation-based x-ray absorption spectroscopy, we provide the first experimental evidence that Russell-Saunders (LS) coupling fails for the 5f states of Pu. These results support the assumption that only the use of jj or intermediate coupling is appropriate for the 5f states of Pu. High energy-electron energy loss spectroscopy experiments were performed by use of a transmission electron microscope and are coupled with image and diffraction data; therefore, the measurements are completely phase specific.
Source PubMed, pmid12785964
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