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26 April 2024
 
  » arxiv » 1310.2373

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Multiferroicity in the geometrically frustrated FeTe2O5Cl
M. Pregelj ; A. Zorko ; O. Zaharko ; P. Jeglič ; Z. Kutnjak ; Z. Jagličić ; S. Jazbec ; H. Luetkens ; A. D. Hillier ; H. Berger ; D. Arčon ;
Date 9 Oct 2013
AbstractThe layered FeTe2O5Cl compound was studied by specic-heat, muon spin relaxation, nuclear magnetic resonance, dielectric, as well as neutron and synchrotron x-ray diffraction measurements, and the results were compared to isostructural FeTe2O5Br. We find that the low-temperature ordered state, similarly as in FeTe2O5Br, is multiferroic - the elliptical amplitude-modulated magnetic cycloid and the net electric polarization simultaneously develop below 11 K. However, compared to FeTe2O5Br, the elliptical envelop rotates by 75(4) deg and the electric polarization is much more sensitive to the applied electric field. We propose the geometric frustration as the most likely mechanism to enhance the effects of otherwise subtle magnetic anisotropy of the Fe3+ (S =5/2) ion and is rather responsible for the observed differences between the two systems. Finally, x-ray diffraction results imply that, on the microscopic scale, the magnetoelectric coupling is driven by shifts of the O1 atoms, as a response to the polarization of the Te4+ lone-pair electrons involved in the Fe-O-Te-O-Fe exchange bridges.
Source arXiv, 1310.2373
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