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26 April 2024
 
  » arxiv » cond-mat/0404092

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Phosphorus cluster production by laser ablation
A.V. Bulgakov ; O.F. Bobrenok ; Igor Ozerov ; W. Marine ; S. Giorgio ; A. Lassesson ; E.E.B. Campbell ;
Date 5 Apr 2004
Journal Applied Physics A 79 (2004) 1369-1372 DOI: 10.1007/s00339-004-2782-z
Subject Materials Science; Chemical Physics; Atomic and Molecular Clusters | cond-mat.mtrl-sci physics.atm-clus physics.chem-ph
AbstractNeutral and charged phosphorus clusters of a wide size range have been produced by pulsed laser ablation (PLA) in vacuum at 532, 337, and 193 nm ablating wavelengths and investigated by time-of-flight mass spectrometry. The neutral P_n clusters are even-numbered with local abundance maxima at n = 10 and 14, while the cationic and anionic clusters are preferentially odd-numbered with (P_7)+, (P_21)+, and (P_17)- being the most abundant ions. The dominance of the magic clusters is more pronounced at 337-nm ablation that is explained by efficient direct ejection of their building blocks under these conditions. Nanocrystalline phosphorus films have been produced by PLA in ambient helium gas.
Source arXiv, cond-mat/0404092
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