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26 April 2024
 
  » arxiv » 2002.3976

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Polymorphic PtBi$_2$ --- candidate for topological superconductivity
G. Shipunov ; I. Kovalchuk ; B. R. Piening ; V. Labracherie ; A. Veyrat ; J. Dufouleur ; S. Shokri ; F. Caglieris ; C. Heß ; D. V. Efremov ; B. Büchner ; S. Aswartham ;
Date 10 Feb 2020
AbstractPtBi$_2$ is a polymorphic system with interesting electronic properties. Here we report optimized crystal growth and structural characterization of pyrite-type and trigonal modification of PtBi$_2$, moreover XRD data analysis and further Rietveld refinement confirms that trigonal PtBi$_2$ crystallizes in non-centrosymmetric $P31m$ space group. Furthermore, we calculate the electronic band structure, using the structure parameters obtained. Series of Pt$_{1-x}$Rh$_x$Bi$_2$ samples was obtained for $x=0, 0.03, 0.35$ which are preserving the trigonal PtBi$_2$ structure. Moreover, we find that at low temperature trigonal-structure Pt$_{1-x}$Rh$_x$Bi$_2$ compounds undergo superconducting transition. The critical temperature increases from $T_c=600$ mK for $x=0$ up to $T_c=2.7$ K for $x=0.35$. The calculated density of states (DOS) shows a minimum for the stochiometric compound at the Fermi level. Due to the topological properties of the electronic band structure material is a candidate for topological superconductivity.
Source arXiv, 2002.3976
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