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26 April 2024
 
  » arxiv » astro-ph/0503587

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H-D Substitution in Interstellar Solid Methanol: A Key Route for D Enrichment
Akihiro Nagaoka ; Naoki Watanabe ; Akira Kouchi ;
Date 28 Mar 2005
Journal Astrophys.J. 624 (2005) L29-L32
Subject astro-ph
AbstractDeuterium enrichment of interstellar methanol is reproduced experimentally for the first time via grain-surface H-D substitution in solid methanol at an atomic D/H ratio of 0.1. Although previous gas-grain models successfully reproduce the deuterium enrichments observed in interstellar methanol molecules (D/H of up to 0.4, compared to the cosmic ratio of $sim 10^{-5})$, the models exclusively focus on deuterium fractionation resulting from the successive addition of atomic hydrogen/deuterium on CO. The mechanism proposed here represents a key route for deuterium enrichment that reproduces the high observed abundances of deuterated methanol, including multiple deuterations.
Source arXiv, astro-ph/0503587
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