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26 April 2024
 
  » arxiv » cond-mat/0507147

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A single molecule switch based on two Pd nanocrystals linked by a conjugated dithiol
Ved Varun Agrawal ; Reji Thomas ; G.U. Kulkarni ; C.N.R. Rao ;
Date 6 Jul 2005
Subject Materials Science; Mesoscopic Systems and Quantum Hall Effect | cond-mat.mtrl-sci cond-mat.mes-hall
AbstractTunneling spectroscopy measurements have been carried out on a single molecule device formed by two Pd nanocrystals (dia, $sim$5 nm) electronically coupled by a conducting molecule, dimercaptodiphenylacetylene. The I-V data, obtained by positioning the tip over a nanocrystal electrode, exhibit negative differential resistance (NDR) on a background M-I-M characteristics. The NDR feature occurs at $sim$0.67 V at 300 K and shifts to a higher bias of 1.93 V at 90 K. When the tip is held in the middle region of the device, a coulomb blockade region is observed ($pmsim$0.3 V).
Source arXiv, cond-mat/0507147
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