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26 April 2024
 
  » arxiv » cond-mat/0606718

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Screening in Yukawa fluid mixtures
A.J. Archer ; P. Hopkins ; R. Evans ;
Date 28 Jun 2006
Subject Soft Condensed Matter; Statistical Mechanics
AbstractThe effective pair potential between mesoscopic charged particles in a neutralising background medium takes a Yukawa form $exp(-lambda r)/r$ with screening length $lambda^{-1}$. We consider a dilute suspension of such Yukawa particles dispersed in a solvent with correlation length $xi<lambda^{-1}$ and show that the Yukawa interaction is `screened’ if the pair potentials between solvent particles exhibit Yukawa decay with the same screening length $lambda^{-1}$. However, if the solvent pair potentials are shorter ranged than the solute Yukawa potentials, then the effective potential between pairs of solute particles is `unscreened’, i.e. the effective potential between the solute particles is equal to the bare potential at large particle separations.
Source arXiv, cond-mat/0606718
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