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Article overview
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A | | C P Collier
; G Mattersteig
; E W Wong
; Y Luo
; K Beverly
; J Sampaio
; F M Raymo
; J F Stoddart
; J R Heath
; | | Date: |
18 Aug 2000 | | Journal: | Science, 289 (5482), 1172-5 | | Abstract: | A solid state, electronically addressable, bistable [2]catenane-based molecular switching device was fabricated from a single monolayer of the [2]catenane, anchored with phospholipid counterions, and sandwiched between an n-type polycrystalline silicon bottom electrode and a metallic top electrode. The device exhibits hysteretic (bistable) current/voltage characteristics. The switch is opened at +2 volts, closed at -2 volts, and read at approximately 0.1 volt and may be recycled many times under ambient conditions. A mechanochemical mechanism for the action of the switch is presented and shown to be consistent with temperature-dependent measurements of the device operation. | | Source: | PubMed, pmid10947980 doi: 8749 | | Services: | Forum | Review | Favorites | |
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